Taken from
Wikipedia:
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Progressive scan (also known as: P-Scan) is used for most cathode ray tube (CRT) computer monitors, all LCD computer monitors, and most HDTVs as the display resolutions are progressive by nature. (Other CRT-type displays, such as SDTVs, typically display interlaced video only)
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Assuming you have a LCD monitor, in theory it should work. However, I've never tried it and there's also this:
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PSP® screen output is 480 x 272. The ability to display games and movies full screen is dependent on your TV Aspect Ratio Controls.
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